RAPPORTO DI PROVA ESITO D'ESAME

RAPPORTO DI PROVA Numero di identificazione Descrizione del campione Arance Tarocco prelevate da committente c/o particella 100 Contrada Carbone - Francoforte (SR) - Azienda Agricola Salvatore Di Marco il 26/02/2018 Campionamento effettuato da: Cliente ( ) Ritiro effettuato da: Richiedente: Corriere E.D.P. SOCIETA' COOPERATIVA VIA CERVIGNANO, 47 CATANIA 95129 CT arrivo campione: 02/03/2018 ( )Il laboratorio declina ogni responsabilità per le modalità di campionamento. MULTIRESIDUALE BASE ESITO D'ESAME * 2-Phenylidrochinone 2-Phenylphenol 4,4-Dichlorobenzophenone * 4-chloro-3-methylphenol (Chlorocresol) 4-Phenylphenol Acephate * Acetochlor Acibenzolar-S-methyl (Sum) Acibenzolar acid Acibenzolar-S-methyl Aclonifen Acrinathrin Alachlor Allethrin Alphamethrin Ametryn Amitraz (included metabolite containing 2,4-DMA expressed as Amitraz) 2,4-Dimetilanilina (2,4 DMA) 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 s 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 Pagina 1 di 15

Amitraz N-2,4-Dimethylphenyl-N'-methylformamidine [DMPF] N-2,4-Dimethylphenyl-formamide [DMF] Atrazine-desethyl Atrazine-desisopropyl Atrazine Azinphos-ethyl Azinphos-methyl Benalaxyl (Sum of benalaxyl and benalaxyl-m) Benfluralin Benzoylprop-ethyl Biphenyl Bifenox Bifenthrin (sum of isomers) Bitertanol (sum of isomers) Boscalid Bromacil * Bromadiolone Bromocyclen Bromophos-ethyl Bromophos-methyl Bromopropylate Bromoxynil (Sum of Bromoxynil and esters expressed as Bromoxynil) Bromoxynil-methyl Bromoxynil-octanoate Bromoxynil Bromuconazole Bupirimate 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 Pagina 2 di 15

Buprofezin 0.010 0.003 * Butaclor Cadusafos Captafol Captan (Sum of Captan and Tetrahydrophthalimide exp as Captan) Captan Tetrahydrophthalimide Carbophenothion-methyl Carbophenothion Carfentrazone-ethyl (Carfentrazone free acid expressed as Carfentrazone-ethyl) Carfentrazone-ethyl Carfentrazone acid Chinomethionat Chlordane (Sum of cis-chlordane and trans-chlordane) cis-chlordane trans-chlordane * Chlordimeform Chlorfenapyr Chlorfenson Chlorfenvinphos Chlormephos Chlorobenzilate Chloropropylate Chlorpyrifos-ethyl Chlorpyrifos-methyl Chlorpropham Chlorthal-dimethyl Chlorothalonil 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.003 0.002 0.003 0.002 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 Pagina 3 di 15

Chlorthiamid Chlorthiophos Chlorthion Chlozolinate Cyhalofop-p-butyl Cyanazin Cyanofenphos Cyanophos Cyflufenamid (Sum of isomer E and Z) Cyfluthrin (Sum of isomers) Cyfluthrin-beta Cymiazole Cypermethrin (Sum of isomers) Cyproconazole Cyprodinil Clodinafop-propargyl Coumaphos DDT (Sum of o-p-ddd, p-p-ddd, o-p-dde, p-p-dde, o-p-ddt, p-p-ddt expressed as DDT) o-p-ddd o-p-dde o-p-ddt p-p-ddd p-p-dde p-p-ddt Deltamethrin Dialifos Diazinon Dichlobenil Diclobutrazol 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 Pagina 4 di 15

Dichlofenthion Dichlofluanid Dichlorvos Diclofop-methyl (Sum of Diclofop-methyl and Diclofop acid expressed as Diclofop-methyl) Diclofop-methyl Diclofop Dicloran Dicofol Dicrotophos Dieldrin (Sum of Dieldrin and Aldrin expressed as Dieldrin) Aldrin Dieldrin Difenoconazole Diflufenican Dimefox * Dimepiperate Diphenamid Dimethoate * Dimetridazole Diniconazole Dinitramine Dipropetryn Disulfoton (Sum of Disulfoton, Disulfoton-sulfone, Disulfoton-sulfoxide expressed as Disulfoton) Disulfoton-sulfone Disulfoton-sulfoxide Disulfoton Ditalimfos Edifenphos < 0.005 mg/kg 0.005 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.003 0.002 0.003 0.002 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.003 0.002 0.003 0.002 0.003 0.002 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 Pagina 5 di 15

Endosulfan (Sum of Alpha and Beta and Sulfate expressed as Endosulfan) alpha-endosulfan beta-endosulfan Endosulfan-sulfate Endrin Endrin aldehyde EPN [O-ethyl O-(4-nitrophenyl) phenylphosphonothioate] Epoxiconazole Esfenvalerate (Sum of Esfenvalerate and Fenvalerate RS+SR e SS+RR) Etaconazole Ethalfluralin Ethion Ethoprophos Etofenprox Etridiazole Etrimfos Fenamiphos (Sum of Fenamiphos and Fenamiphos-sulfone, Fenamiphos-sulfoxide expressed as Fenamiphos) Fenamiphos-sulfone Fenamiphos-sulfoxide Fenamiphos Fenarimol Fenbuconazole Fenchlorphos (Sum of Fenchlorphos and Fenchlorphos-oxon expressed as Fenchlorphos) Fenchlorphos-oxon Fenchlorphos Fenhexamid Fenitrothion 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 Pagina 6 di 15

* Fenobucarb Fenothiocarb Fenoxaprop-p-ethyl (Sum of Fenoxaprop-p-ethyl and Fenoxaprop- acid) Fenoxaprop (Fenoxaprop-p included) Fenoxaprop-p-ethyl Fenpropathrin Fenpropimorph (sum of isomers) Fenson Fenthion (Sum) Fenthion-oxon-sulfone Fenthion-oxon-sulfoxide Fenthion-oxon Fenthion-sulfone Fenthion-sulfoxide Fenthion Fipronil (Sum of Fipronil and Fipronil Sulfone expressed as Fipronil) Fipronil-sulfone Fipronil Fipronil-desulfinyl Flamprop-isopropyl Flonicamid (Sum of Flonicamid and TFNA, TFNG expressed as Flonicamid) Flonicamid TFNA TFNG Fluazifop-P-butyl (Sum of Fluazifop-P-butyl and Fluazifop) Fluazifop-P-butyl Fluazifop Fluazinam 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg t < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.003 0.002 0.003 0.002 0.003 0.002 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 Pagina 7 di 15

Flubenzimine Flucythrinate Fluchloralin Fludioxonil Flufenacet Fluopicolide Fluotrimazole Fluquiconazole Fluridone Flurochloridone Flurprimidol Flusilazole Fluthiacet-methyl Flutolanil Flutriafol Folpet (Sum of Folpet and Phtalimide expressed as Folpet) Folpet Phthalimide Fonofos Formothion Fosthiazate Furalaxyl Haloxyfop (Sum) Haloxyfop Haloxyfop-2-ethoxyethyl Haloxyfop-methyl HCH (Hexachlorocyclohexane) (Sum of isomers Alpha, Beta, Delta and Epsilon) alpha-hch 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 r 0.010 0.003 0.010 0.003 0.010 0.003 0.003 0.002 Pagina 8 di 15

beta-hch 0.003 0.002 delta-hch epsilon-hch gamma HCH [Lindane] Heptachlor (Sum of Heptachlor and cis and trans Heptachloroepoxide expressed as Heptachlor) cis-heptachloroepoxide Heptachlor trans-heptachloroepoxide Heptenophos Hexachlorobenzene Hexaconazole Hexazinone Imazalil * Imibenconazole Indoxacarb (Sum of indoxacarb and its enantiomer R) Iodofenphos Iprodione Isazophos Isocarbophos Isodrin Isofenphos-methyl Isofenphos Isopropalin Isoxaben Isoxadifen-ethyl Isoxathion lambda-cyhalothrin Lenacil Leptophos 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 0.003 0.002 < 0.005 mg/kg 0.005 0.003 0.003 0.002 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 Pagina 9 di 15

Malathion (Sum of Malathion and Malaoxon expressed as Malathion) Malaoxon Malathion Mecarbam Mepanipyrim Metalaxyl and Metalaxyl-M (Sum) Methacrifos Methamidophos Metazachlor Metconazole Metidathion Metolachlor (Sum of Metolachlor and Metolachlor-S) * Methoprotryne Methoxychlor Metribuzin Mevinphos (Sum of isomer E and Z) * Mgk-264 Myclobutanil Mirex Monocrotophos Naled Napropamide Nitrapyrin Nitrofen Nitrothal-isopropyl Nuarimol Omethoate Oxadiazon Oxadixyl < 0.005 mg/kg < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 q < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.003 0.002 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.003 0.002 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 Pagina 10 di 15

Oxyfluorfen Paclobutrazol Paraoxon-ethyl Parathion-ethyl Parathion-methyl (Sum of Parathion-methyl and Paraoxon-methyl expressed as Parathion-methyl) Paraoxon-methyl Parathion-methyl Pencycuron Penconazole Pendimethalin Pentachloroanisole Pentachlorobenzene Pentachlorophenol Phenmedipham Phenthoate Permethrin Perthane Phorate (Sum of Phorate and Phorate-oxon, Phorate-sulfone, Phorate-sulfoxide expressed as Phorate) Phorate Phorate-oxon Phorate-sulfone Phorate-sulfoxide Phosalone Phosmet (Sum of Phosmet and Phosmet oxon expressed as Phosmet) Phosmet Phosmet oxon Phosphamidon Picolinafen 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.003 0.002 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 Pagina 11 di 15

Piperonyl butoxide Pirimicarb (Sum of Pirimicarb and Pirimicarb-desmethyl expressed as Pirimicarb) Pirimicarb-desmethyl Pirimicarb Pirimiphos-ethyl Pirimiphos-methyl Procymidone Prochloraz (Prochloraz included metabolite containing 2,4,6-Trichlorophenol exp as Prochloraz) 2,4,6-Trichlorophenol Prochloraz Propham Profenofos Profluralin Prometon Prometryn Propachlor Propanil Propazine Propiconazole Propyzamide Proquinazid * Pyraflufen-ethyl Pyrazophos Pyrethrins Pyridaben Pyridaphenthion Pyrifenox Pyrimethanil 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 Pagina 12 di 15

Prothioconazole-desthio 0.010 0.003 Prothioconazole Prothiophos Prothoate Quinalphos Quinoxyfen Quintozene (Sum of Quintozene and Penthachloroaniline expressed as Quintozene) Pentachloroaniline Quintozene Quizalofop-p-ethyl (Sum of Quizalofop-p-ethyl and Quizalofop-P acid) Quizalofop-p-ethyl Quizalofop acid S 421 Silaneophan [Silafluofen] Simazine Simetryn Spirodiclofen Spiromesifen Spiroxamine Sulfotep tau-fluvalinate Tebuconazole Tebufenpyrad Tebupirimfos Tecnazene Tefluthrin Terbacil Terbufos 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.003 0.002 Pagina 13 di 15

Terbumeton 0.010 0.003 Terbuthylazine-desethyl Terbuthylazine Terbutryn Tetrachlorvinphos Tetraconazole Tetradifon Tetramethrin Tetrasul * Tiocarbazil Thionazin Tolclofos-methyl Tolylfluanid (Sum of Tolylfluanid and DMST expressed as Tolylfluanid) DMST (Dimethylaminolsulftoluidide) Tolylfluanid Transfluthrin Triadimefon Triadimenol Triazophos Tricyclazole Trichlorfon Trichloronat Trifloxystrobin Triflumizole (Sum of Triflumizole and FM-6 exp as Triflumizole) FM-6 Triflumizole Trifluralin Triticonazole 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 0.010 0.003 Pagina 14 di 15

Valiphenalat 0.010 0.003 Vamidothion Vinclozolin Zoxamide < 0.005 mg/kg 0.005 0.003 0.010 0.003 0.010 0.003 Legenda: Inc (Incertezza); u.m. (unità di misura); LOQ (limite di quantificazione); LOD (limite di determinazione); Rec. (recupero); u.o. (unità operativa); (prova eseguita presso u.o. via Sangallo); 0_B (prova eseguita presso u.o. via Bramante); II (lab. mobili); III (analisi in esterna); LE.# (prova eseguita in subappalto c/o laboratorio terzo); NOTE lettere: q) Metalaxyl and Metalaxyl-M (Metalaxyl including other mixtures of constituent isomers including Metalaxyl-M (sum of isomers)) r) Haloxyfop (Sum of Haloxyfop, its esters, salts and conjugates expressed as Haloxyfop (sum of the R- and S- isomers at any ratio)) s) Acibenzolar-S-methyl (Sum of Acibenzolar-S-methyl and Acibenzolar acid espressed as Acibenzolar-S-methyl) t) Fenthion (Sum of Fenthion and Fenthion-oxon, Fenthion-oxon-sulfone, Fenthion-oxon-sulfoxide, Fenthion-sulfone, Fenthion-sulfoxide espressed as Fenthion) generali: Per le prove chimiche, i valori di incertezza estesa sono riferiti ad un intervallo di confidenza del 95%. Fattore di copertura k=2. Dove non indicato diversamente, il limite di determinazione (LOD) risulta uguale a 3/10LOQ. Per le prove multiresiduali i controlli di qualità previsti dal metodo sono stati verificati. Per le prove multiresiduali, i risultati forniti sono corretti per il recupero. I risultati riportati sono riferiti al solo campione sottoposto a prova. (* prova non accreditata da ACCREDIA) I campioni alimentari ed i campioni non deteriorabili sottoposti ad analisi sono conservati per 30 giorni dalla data di arrivo del campione. Campioni di acque, compost e di altre matrici deteriorabili sono conservati fino all'emissione del Rapporto di. Li, 06/03/2018 per il Responsabile di Laboratorio dott. Fabrizio Ferraro ph srl è iscritta al numero 013 dell'elenco regionale dei laboratori che effettuano analisi nell'ambito delle procedure di autocontrollo delle industrie alimentari (L.R. Toscana n 9 09/03/2006). Il presente rapporto di prova non può essere riprodotto in forma parziale salvo l'approvazione scritta del Laboratorio. Il rapporto di prova originale viene fornito in formato digitale, file.p7m, firmato con sistema di firma digitale certificata dal responsabile autorizzato. Eventuali copie stampate del suddetto documento digitale originale non hanno validità legale. Pagina 15 di 15